Literature DB >> 24123576

Solvation of carbon dioxide in [C4 mim][BF(4)] and [C(4) mim][PF(6)] ionic liquids revealed by high-pressure NMR spectroscopy.

Marta C Corvo1, João Sardinha, Sonia C Menezes, Sandra Einloft, Marcus Seferin, Jairton Dupont, Teresa Casimiro, Eurico J Cabrita.   

Abstract

Where is CO2 ? The intermolecular interactions of [C4 mim]BF4 and [C4 mim]PF6 ionic liquids and CO2 have been determined by high-pressure NMR spectroscopy in combination with molecular dynamic simulations. The anion and the cation are both engaged in interactions with CO2 . A detailed picture of CO2 solvation in these ILs is provided. CO2 solubility is essentially determined by the microscopic structure of the IL.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CO2 sequestration; NMR spectroscopy; ionic liquids; molecular dynamics

Year:  2013        PMID： 24123576     DOI： 10.1002/anie.201305630

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  BODIPY-BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids.

Authors:  Joseph D Kimball; Sangram Raut; Laramie P Jameson; Nicholas W Smith; Zygmunt Gryczynski; Sergei V Dzyuba
Journal:  RSC Adv       Date:  2015       Impact factor: 3.361

Review 2.  Recent advances in liquid hydrosilane-mediated catalytic N-formylation of amines with CO2.

Authors:  Zhengyi Li; Zhaozhuo Yu; Xiaoxiang Luo; Chuanhui Li; Hongguo Wu; Wenfeng Zhao; Hu Li; Song Yang
Journal:  RSC Adv       Date:  2020-09-14       Impact factor: 4.036

Review 3.  Revisiting Ionic Liquid Structure-Property Relationship: A Critical Analysis.

Authors:  Wagner Silva; Marcileia Zanatta; Ana Sofia Ferreira; Marta C Corvo; Eurico J Cabrita
Journal:  Int J Mol Sci       Date:  2020-10-19       Impact factor: 5.923
  3 in total

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