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Literature DB >> 24123575

Tetrel-bonding interaction: rediscovered supramolecular force?

Antonio Bauzá¹, Tiddo J Mooibroek, Antonio Frontera.

Abstract

The w(hole) picture: A tetrel bond is a directional noncovalent interaction between a covalently bonded atom of Group IV and a negative site, for example, the lone pair of a Lewis base or an anion. It involves a region of positive electrostatic potential (σ hole), and energetically, they are comparable to hydrogen bonds and other σ-hole-based interactions.

Entities: Chemical

Keywords: ab initio calculations; group 14 elements; noncovalent interactions; silicon; supramolecular chemistry

Year: 2013 PMID： 24123575 DOI： 10.1002/anie.201306501

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

57 in total

1. Cooperative effects between halogen bonds and pnicogen bonds in XBr∙∙∙OFH2P∙∙∙NH3 (X = F, Cl, CN, NC, OH, and NO2) complexes.

Authors: Qiang Zhao
Journal: J Mol Model Date: 2015-12-09 Impact factor: 1.810

2. Theoretical study of the cooperative effects between the triel bond and the pnicogen bond in BF3···NCXH2···Y (X = P, As, Sb; Y = H2O, NH3) complexes.

Authors: Ming-Xiu Liu; Hong-Ying Zhuo; Qing-Zhong Li; Wen-Zuo Li; Jian-Bo Cheng
Journal: J Mol Model Date: 2015-12-16 Impact factor: 1.810

Tetrel-bonding interaction: rediscovered supramolecular force?

1. Cooperative effects between halogen bonds and pnicogen bonds in XBr∙∙∙OFH2P∙∙∙NH3 (X = F, Cl, CN, NC, OH, and NO2) complexes.

2. Theoretical study of the cooperative effects between the triel bond and the pnicogen bond in BF3···NCXH2···Y (X = P, As, Sb; Y = H2O, NH3) complexes.

3. On the reciprocal relationship between σ-hole bonding and (anti)aromaticity gain in ketocyclopolyenes.

4. Dual functions of Lewis acid and base of Se in F2C=Se and their interplay in F 2CSe•••NH 3•••HX.

5. Theoretical study of noncovalent interactions in XCN···YO₂H (X = F, Cl, Br, I; Y = P, As, Sb) complexes.

6. Quantum-mechanical investigation of tetrel bond characteristics based on the point-of-charge (PoC) approach.

7. Synergistic and antagonistic interplay between tetrel bond and pnicogen bond in complexes involving ring compounds.

8. Competition between π-hole interaction and hydrogen bond in the complexes of F2XO (X = C and Si) and HCN.

9. Modulating the strength of tetrel bonding through beryllium bonding.

10. Chalcogen- and halogen-bonds involving SX2 (X = F, Cl, and Br) with formaldehyde.