Literature DB >> 24121786

Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex.

Sonja N König1, Nicholas F Chilton, Cäcilia Maichle-Mössmer, Eufemio Moreno Pineda, Thomas Pugh, Reiner Anwander, Richard A Layfield.   

Abstract

Ab initio calculations on the octahedral dysprosium aluminate complex [Dy(AlMe4)3] (1) predict weak SMM properties. Dynamic magnetic susceptibility measurements on 1 confirm the theoretical predictions, revealing fast relaxation of the magnetization via quantum tunnelling.

Entities:  

Year:  2014        PMID： 24121786     DOI： 10.1039/c3dt52337c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

Review 1.  Rare Earth Starting Materials and Methodologies for Synthetic Chemistry.

Authors:  Fabrizio Ortu
Journal:  Chem Rev       Date:  2022-01-31       Impact factor: 60.622

2.  Hydroxide-bridged five-coordinate DyIII single-molecule magnet exhibiting the record thermal relaxation barrier of magnetization among lanthanide-only dimers.

Authors:  Jin Xiong; Hai-Yan Ding; Yin-Shan Meng; Chen Gao; Xue-Jing Zhang; Zhao-Sha Meng; Yi-Quan Zhang; Wei Shi; Bing-Wu Wang; Song Gao
Journal:  Chem Sci       Date:  2016-10-30       Impact factor: 9.825

3.  C-H-Bond Activation and Isoprene Polymerization Studies Applying Pentamethylcyclopentadienyl-Supported Rare-Earth-Metal Bis(Tetramethylaluminate) and Dimethyl Complexes.

Authors:  Christoph O Hollfelder; Melanie Meermann-Zimmermann; Georgios Spiridopoulos; Daniel Werner; Karl W Törnroos; Cäcilia Maichle-Mössmer; Reiner Anwander
Journal:  Molecules       Date:  2019-10-15       Impact factor: 4.411
  3 in total

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