Literature DB >> 24117331

The rearrangement of tert-butylperoxides for the construction of polysubstituted furans.

Xiaojian Zheng1, Shenglin Lu, Zhiping Li.   

Abstract

The Brønsted acid catalyzed rearrangement of tert-butyl peroxides provides a new strategy to construct 2,3-disubstituted furans via 1,2-aryl migration. In addition, tert-butyl peroxides could also be transformed into 2,3,5-trisubstituted or 2,5-disubstituted furans through a sequence of base-catalyzed Kornblum-DelaMare rearrangements and acid-promoted Paal-Knorr reactions.

Entities:  

Year:  2013        PMID: 24117331     DOI: 10.1021/ol402509u

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

Review 1.  Rearrangements of organic peroxides and related processes.

Authors:  Ivan A Yaremenko; Vera A Vil'; Dmitry V Demchuk; Alexander O Terent'ev
Journal:  Beilstein J Org Chem       Date:  2016-08-03       Impact factor: 2.883

2.  Silver-Catalyzed Controlled Intermolecular Cross-Coupling of Silyl Enol Ethers: Scalable Access to 1,4-Diketones.

Authors:  Li Xu; Xiaoyi Liu; Gregory R Alvey; Andrey Shatskiy; Jian-Quan Liu; Markus D Kärkäs; Xiang-Shan Wang
Journal:  Org Lett       Date:  2022-06-17       Impact factor: 6.072

3.  Stereoselective synthesis of hernandulcin, peroxylippidulcine A, lippidulcines A, B and C and taste evaluation.

Authors:  Marco Giulio Rigamonti; Francesco Gilberto Gatti
Journal:  Beilstein J Org Chem       Date:  2015-11-05       Impact factor: 2.883

  3 in total

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