Literature DB >> 24117158

Isolation of the large {actinide}38 poly-oxo cluster with uranium.

Clément Falaise1, Christophe Volkringer, Jean-François Vigier, Arnaud Beaurain, Pascal Roussel, Pierre Rabu, Thierry Loiseau.   

Abstract

By controlling the water content, a new poly-oxo-metalate species containing 38 uranium centers has been solvothermally synthesized in the presence of benzoic acid in tetrahydrofuran (THF). The {U38} motif contains a distorted UO2 core of fluorite type, stabilized by benzoate and THF molecules. This compound is analogous to the {Pu38} motif and was characterized by X-ray photoelectron spectroscopy and magnetic analyses.

Entities:  

Year:  2013        PMID： 24117158     DOI： 10.1021/ja4067207

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  One-dimensional chain structures of hexanuclear uranium(iv) clusters bridged by formate ligands.

Authors:  Jie Ling; Huangjie Lu; Yaxing Wang; Kenndra Johnson; Shuao Wang
Journal:  RSC Adv       Date:  2018-10-12       Impact factor: 4.036

2.  Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)2 followed by the formation of molecular poly-oxo cluster {U14} containing hemimellitate uranium(iv).

Authors:  Maxime Dufaye; Nicolas P Martin; Sylvain Duval; Christophe Volkringer; Atsushi Ikeda-Ohno; Thierry Loiseau
Journal:  RSC Adv       Date:  2019-07-23       Impact factor: 4.036

3.  Formation of a new type of uranium(iv) poly-oxo cluster {U38} based on a controlled release of water via esterification reaction.

Authors:  Nicolas P Martin; Christophe Volkringer; Natacha Henry; Xavier Trivelli; Grégory Stoclet; Atsushi Ikeda-Ohno; Thierry Loiseau
Journal:  Chem Sci       Date:  2018-05-09       Impact factor: 9.825
  3 in total

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