Literature DB >> 24116627

Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions.

M Auzinsh1, E I Dashevskaya, I Litvin, E E Nikitin, J Troe.   

Abstract

Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H(+), D(+), and H3(+) are calculated.

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Year:  2013        PMID: 24116627     DOI: 10.1063/1.4821589

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  2 in total

1.  Multipole-moment effects in ion-molecule reactions at low temperatures: part III - the He+ + CH4 and He+ + CD4 reactions at low collision energies and the effect of the charge-octupole interaction.

Authors:  Valentina Zhelyazkova; Fernanda B V Martins; Frédéric Merkt
Journal:  Phys Chem Chem Phys       Date:  2022-07-06       Impact factor: 3.945

2.  Multipole-moment effects in ion-molecule reactions at low temperatures: part II - charge-quadrupole-interaction-induced suppression of the He+ + N2 reaction at collision energies below kB·10 K.

Authors:  Valentina Zhelyazkova; Fernanda B V Martins; Matija Žeško; Frédéric Merkt
Journal:  Phys Chem Chem Phys       Date:  2022-02-02       Impact factor: 3.676

  2 in total

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