Literature DB >> 24115611

Nickel-catalyzed sonogashira reactions of non-activated secondary alkyl bromides and iodides.

Jun Yi1, Xi Lu, Yan-Yan Sun, Bin Xiao, Lei Liu.   

Abstract

A nicked reaction: The title reaction of terminal alkynes with non-activated secondary alkyl iodides and bromides was accomplished for the first time. This reaction provides a new and practical approach for the synthesis of substituted alkynes (see scheme; cod=cyclo-1,5-octadiene).
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkynes; cross-coupling; halides; nickel; synthetic methods

Mesh：

Substances：

Year:  2013        PMID： 24115611     DOI： 10.1002/anie.201307069

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Reductive Decarboxylative Alkynylation of N-Hydroxyphthalimide Esters with Bromoalkynes.

Authors:  Liangbin Huang; Astrid M Olivares; Daniel J Weix
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-17       Impact factor: 15.336

2.  SOMOphilic Alkynylation of Unreactive Alkenes Enabled by Iron-Catalyzed Hydrogen Atom Transfer.

Authors:  Binlin Zhao; Tianxiang Zhu; Mengtao Ma; Zhuangzhi Shi
Journal:  Molecules       Date:  2021-12-22       Impact factor: 4.411

3.  A Modular Synthesis of Teraryl-Based α-Helix Mimetics, Part 5: A Complete Set of Pyridine Boronic Acid Pinacol Esters Featuring Side Chains of Proteinogenic Amino Acids.

Authors:  Melanie Trobe; Till Schreiner; Martin Vareka; Sebastian Grimm; Bernhard Wölfl; Rolf Breinbauer
Journal:  European J Org Chem       Date:  2022-02-24

4.  Multimetallic catalysed radical oxidative C(sp(3))-H/C(sp)-H cross-coupling between unactivated alkanes and terminal alkynes.

Authors:  Shan Tang; Pan Wang; Haoran Li; Aiwen Lei
Journal:  Nat Commun       Date:  2016-06-24       Impact factor: 14.919
  4 in total

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