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Literature DB >> 24115562

Selective methylation of amines with carbon dioxide and H₂.

Yuehui Li¹, Iván Sorribes, Tao Yan, Kathrin Junge, Matthias Beller.

Abstract

Entities: Chemical

Keywords: homogeneous catalysis; hydrogen; methylation; reduction; ruthenium

Year: 2013 PMID： 24115562 DOI： 10.1002/anie.201306850

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

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12 in total

1. N-formylation and N-methylation of amines using metal-free N-heterocyclic carbene catalysts and CO₂ as carbon source.

Authors: Felix D Bobbink; Shoubhik Das; Paul J Dyson
Journal: Nat Protoc Date: 2017-01-26 Impact factor: 13.491

2. Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.

Authors: Saravanakumar Elangovan; Jacob Neumann; Jean-Baptiste Sortais; Kathrin Junge; Christophe Darcel; Matthias Beller
Journal: Nat Commun Date: 2016-10-06 Impact factor: 14.919

3. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

Authors: Yu Lu; Zhong-Hua Gao; Xiang-Yu Chen; Jiandong Guo; Zheyuan Liu; Yanfeng Dang; Song Ye; Zhi-Xiang Wang
Journal: Chem Sci Date: 2017-09-11 Impact factor: 9.825

4. Semiconductor photocatalysis to engineering deuterated N-alkyl pharmaceuticals enabled by synergistic activation of water and alkanols.

Authors: Zhaofei Zhang; Chuntian Qiu; Yangsen Xu; Qing Han; Junwang Tang; Kian Ping Loh; Chenliang Su
Journal: Nat Commun Date: 2020-09-18 Impact factor: 14.919

Selective methylation of amines with carbon dioxide and H₂.

1. N-formylation and N-methylation of amines using metal-free N-heterocyclic carbene catalysts and CO₂ as carbon source.

2. Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.

3. Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO₂, and hydrosilane catalyzed by 1,3,2-diazaphospholene?

4. Semiconductor photocatalysis to engineering deuterated N-alkyl pharmaceuticals enabled by synergistic activation of water and alkanols.

5. Cobalt-catalysed reductive C-H alkylation of indoles using carboxylic acids and molecular hydrogen.

6. Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.

7. Convenient iron-catalyzed reductive aminations without hydrogen for selective synthesis of N-methylamines.

8. N,N-Dimethylation of nitrobenzenes with CO₂ and water by electrocatalysis.

9. Direct Photochemical C-H Carboxylation of Aromatic Diamines with CO₂ under Electron-Donor- and Base-free Conditions.

10. Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines.