| Literature DB >> 24108593 |
Stéphanie Dupuy1, Steven P Nolan.
Abstract
Golden delivery: A gold(I)-NHC complex catalyses the protodecarboxylation of various (hetero)aromatic acids. This methodology is simple, highly efficient and combines both the advantages of copper and silver methods with applications to completely deactivated substrates. Moreover, intermediates in this reaction have been isolated and fully characterized and provide fundamental insights into the mechanism of protodecarboxylation with gold.Entities:
Keywords: N-heterocyclic carbene; catalysis; decarboxylation; gold; protodeauration
Year: 2013 PMID： 24108593 DOI： 10.1002/chem.201303200
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236