Literature DB >> 24105906

LCST-type phase behavior induced by pillar[5]arene/ionic liquid host-guest complexation.

Shengyi Dong1, Bo Zheng, Yong Yao, Chengyou Han, Jiayin Yuan, Markus Antonietti, Feihe Huang.   

Abstract

The host-guest complex of dipropoxypillar[5]arene and an ionic liquid 1,3-dimethylimidazolium iodide is found to exhibit a lower critical solution temperature (LCST)-type phase transition in chloroform. This LCST-type phase behavior can be conveniently modulated by experimental parameters and can be easily combined with the ionic liquid for potential application in product and educt separation.
© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  host-guest systems; ionic liquids; lower critical solution temperature; pillararenes; supramolecular chemistry

Year:  2013        PMID: 24105906     DOI: 10.1002/adma.201303652

Source DB:  PubMed          Journal:  Adv Mater        ISSN: 0935-9648            Impact factor:   30.849


  5 in total

1.  DFT/TDDFT investigation on the chemical reactivities, aromatic properties, and UV-Vis absorption spectra of 1-butoxy-4-methoxybenzenepillar[5]arene constitutional isomers.

Authors:  Jian Zhang; Shuqing Ren
Journal:  J Mol Model       Date:  2016-08-17       Impact factor: 1.810

2.  An amphiphilic pseudo[1]catenane: neutral guest-induced clouding point change.

Authors:  Tomoki Ogoshi; Tomohiro Akutsu; Tada-Aki Yamagishi
Journal:  Beilstein J Org Chem       Date:  2018-07-26       Impact factor: 2.883

3.  Enhancing Mechanical Performance of a Polymer Material by Incorporating Pillar[5]arene-Based Host-Guest Interactions.

Authors:  Chengdi Huang; Hanwei Zhang; Ziqing Hu; Youping Zhang; Xiaofan Ji
Journal:  Gels       Date:  2022-07-28

4.  Warm/cool-tone switchable thermochromic material for smart windows by orthogonally integrating properties of pillar[6]arene and ferrocene.

Authors:  Sai Wang; Zuqiang Xu; Tingting Wang; Tangxin Xiao; Xiao-Yu Hu; Ying-Zhong Shen; Leyong Wang
Journal:  Nat Commun       Date:  2018-04-30       Impact factor: 14.919

5.  "Inverse" thermoresponse: heat-induced double-helix formation of an ethynylhelicene oligomer with tri(ethylene glycol) termini.

Authors:  Nozomi Saito; Higashi Kobayashi; Masahiko Yamaguchi
Journal:  Chem Sci       Date:  2016-02-12       Impact factor: 9.825

  5 in total

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