| Literature DB >> 24100414 |
Fareed Bhasha Sayyed1, Yasushi Tsuji, Shigeyoshi Sakaki.
Abstract
In Ni(0)-catalyzed carboxylation reaction of aryl chloride with CO2, the formation of a Ni(I) species is crucial, because the CO2 insertion into the Ni(I)-Ph bond easily occurs but that into the Ni(II)-Ph bond cannot. This is a key point of this successful carboxylation reaction.Entities:
Year: 2013 PMID： 24100414 DOI： 10.1039/c3cc45836a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222