Boosting photoabsorption by attosecond control of electron correlation.

Electron correlation plays an essential role in a wide range of fundamentally important many-body phenomena in modern physics and chemistry. An example is the importance of electron-electron correlation in multiple ionization of multielectron atoms and molecules exposed to intense laser pulses. Manipulating the dynamic electron correlation in such photoinduced processes is a crucial step toward the coherent control of chemical reactions and photobiological processes. The generation of an attosecond extreme ultraviolet (EUV) pulse may enable such controls. Here, we show for the first time, from full-dimensional ab initio calculations of double ionization of helium in intense laser pulses (λ = 780 nm), that the electron-electron interactions can be instantaneously tuned using a time-delayed attosecond EUV pulse. Consequently, the probability of producing energetic electrons from excessive photoabsorption can be enhanced by an order of magnitude, by the attosecond control of electron-electron correlation.