Literature DB >> 24090251

Ir-catalyzed preparation of SF5-substituted potassium aryl trifluoroborates via C-H borylation and their application in the Suzuki-Miyaura reaction.

Adrien Joliton1, Erick M Carreira.   

Abstract

The preparation of new pentafluorosulfanyl-substituted potassium aryltrifluoroborates via Ir-catalyzed C-H borylation is reported. The utility of these novel building blocks was demonstrated in the Suzuki-Miyaura cross-coupling reaction, giving access to 3,5-disubstituted pentafluorosulfanylbenzenes.

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Year:  2013        PMID： 24090251     DOI： 10.1021/ol4025666

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes.

Authors:  George Iakobson; Junyi Du; Alexandra M Z Slawin; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2015-08-26       Impact factor: 2.883

2.  Synthesis of Phthalocyanines with a Pentafluorosulfanyl Substituent at Peripheral Positions.

Authors:  Norihito Iida; Kenta Tanaka; Etsuko Tokunaga; Satoru Mori; Norimichi Saito; Norio Shibata
Journal:  ChemistryOpen       Date:  2015-07-24       Impact factor: 2.911

3.  Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design.

Authors:  Yuji Sumii; Kenta Sasaki; Seiji Tsuzuki; Norio Shibata
Journal:  Molecules       Date:  2019-10-07       Impact factor: 4.411

4.  Synthesis and nucleophilic aromatic substitution of 3-fluoro-5-nitro-1-(pentafluorosulfanyl)benzene.

Authors:  Javier Ajenjo; Martin Greenhall; Camillo Zarantonello; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2016-02-03       Impact factor: 2.883
  4 in total

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