| Literature DB >> 24084795 |
Christian A Citron1, Jeroen S Dickschat.
Abstract
The biosynthesis of tricho-acorenol in Trichoderma harzianum was investigated by feeding stereospecifically deuterated mevalonolactone isotopomers, followed by a detailed GC/MS analysis of the incorporation of labelling. The results establish a highly stereospecific hydride migration and antarafacial attack of water in the terminal step towards tricho-acorenol.Entities:
Mesh：
Substances：
Year: 2013 PMID： 24084795 DOI： 10.1039/c3ob41755g
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876