Literature DB >> 24081311

Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis.

Mirim Kim1, Jihye Park, Satyasheel Sharma, Sangil Han, Sang Hoon Han, Jong Hwan Kwak, Young Hoon Jung, In Su Kim.   

Abstract

Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.

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Year:  2013        PMID： 24081311     DOI： 10.1039/c3ob41828f

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  4 in total

1.  A novel Pd-catalysed sequential carbonylation/cyclization approach toward bis-N-heterocycles: rationalization by electronic structure calculations.

Authors:  Liliana Damas; Rui M B Carrilho; Sandra C C Nunes; Alberto A C C Pais; László Kollár; Marta Pineiro; Mariette M Pereira
Journal:  R Soc Open Sci       Date:  2018-09-12       Impact factor: 2.963

2.  Polarclean/Water as a Safe and Recoverable Medium for Selective C2-Arylation of Indoles Catalyzed by Pd/C.

Authors:  Filippo Campana; Beatrice Maria Massaccesi; Stefano Santoro; Oriana Piermatti; Luigi Vaccaro
Journal:  ACS Sustain Chem Eng       Date:  2020-10-27       Impact factor: 8.198

3.  Synthesis of Functionalized Indoles via Palladium-Catalyzed Cyclization of N-(2-allylphenyl) Benzamide: A Method for Synthesis of Indomethacin Precursor.

Authors:  Zhe Chang; Tong Ma; Yu Zhang; Zheng Dong; Heng Zhao; Depeng Zhao
Journal:  Molecules       Date:  2020-03-09       Impact factor: 4.411

4.  Mild and Practical Indole C2 Allylation by Allylboration of in situ Generated 3-Chloroindolenines.

Authors:  Jordy M Saya; Ellen D H van Wordragen; Romano V A Orru; Eelco Ruijter
Journal:  European J Org Chem       Date:  2019-01-17
  4 in total

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