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Literature DB >> 24051607

Electrochemistry of Au(II) and Au(III) pincer complexes: determination of the Au(II)-Au(II) bond energy.

Thomas Dann¹, Dragoş-Adrian Roşca, Joseph A Wright, Gregory G Wildgoose, Manfred Bochmann.

Abstract

The bond energy of the unsupported Au-Au bond in the Au(ii) dimer [(C(∧)N(∧)C)Au]2 and the difference between Au(III)-OH and Au(III)-H bond enthalpies have been determined experimentally by electrochemical methods, with Au-OH and Au-H complexes showing unexpected differences in their reduction pathways, supported by DFT modelling.

Entities: Chemical Gene

Year: 2013 PMID： 24051607 DOI： 10.1039/c3cc45984e

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

9 in total

1. Structure and reactivity of a mononuclear gold(II) complex.

Authors: Sebastian Preiß; Christoph Förster; Sven Otto; Matthias Bauer; Patrick Müller; Dariush Hinderberger; Haleh Hashemi Haeri; Luca Carella; Katja Heinze
Journal: Nat Chem Date: 2017-08-07 Impact factor: 24.427

2. Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF₂ )_n Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation.

Authors: Alejandro Portugués; Delia Bautista; Juan Gil-Rubio
Journal: Chemistry Date: 2021-09-29 Impact factor: 5.020

3. Reactivity of the [Au(C^N^C)Cl] complex in the presence of H₂O and N-, S- and Se-containing nucleophiles: a DFT study.

Authors: G Y Sánchez Delgado; D Paschoal; H F Dos Santos
Journal: J Biol Inorg Chem Date: 2018-09-12 Impact factor: 3.358

4. Synthesis, Photochemical, and Redox Properties of Gold(I) and Gold(III) Pincer Complexes Incorporating a 2,2':6',2"-Terpyridine Ligand Framework.

Authors: M Concepción Gimeno; José M López-de-Luzuriaga; Elena Manso; Miguel Monge; M Elena Olmos; María Rodríguez-Castillo; María-Teresa Tena; David P Day; Elliot J Lawrence; Gregory G Wildgoose
Journal: Inorg Chem Date: 2015-10-23 Impact factor: 5.165

Electrochemistry of Au(II) and Au(III) pincer complexes: determination of the Au(II)-Au(II) bond energy.

1. Structure and reactivity of a mononuclear gold(II) complex.

2. Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF₂ )_n Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation.

3. Reactivity of the [Au(C^N^C)Cl] complex in the presence of H₂O and N-, S- and Se-containing nucleophiles: a DFT study.

4. Synthesis, Photochemical, and Redox Properties of Gold(I) and Gold(III) Pincer Complexes Incorporating a 2,2':6',2"-Terpyridine Ligand Framework.

5. Stereo- and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides.

6. Formation of Gold(III) Alkyls from Gold Alkoxide Complexes.

7. An element through the looking glass: exploring the Au-C, Au-H and Au-O energy landscape.

8. Gold(III)-CO and gold(III)-CO2 complexes and their role in the water-gas shift reaction.

Review 9. Excimer and Exciplex Formation in Gold(I) Complexes Preconditioned by Aurophilic Interactions.