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Literature DB >> 24048438

Cobalt-catalyzed transfer hydrogenation of C=O and C=N bonds.

Abstract

An earth-abundant metal cobalt catalyst has been developed for the transfer hydrogenation of ketones, aldehydes, and imines under mild conditions. Experiments are described which provide insights into the mechanism of the transfer hydrogenation reaction.

Entities: Chemical

Year: 2013 PMID： 24048438 DOI： 10.1039/c3cc45900d

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. Alkene Metalates as Hydrogenation Catalysts.

Authors: Philipp Büschelberger; Dominik Gärtner; Efrain Reyes-Rodriguez; Friedrich Kreyenschmidt; Konrad Koszinowski; Axel Jacobi von Wangelin; Robert Wolf
Journal: Chemistry Date: 2017-02-06 Impact factor: 5.236

2. Roles of Hydrogen Bonding in Proton Transfer to κ^P,κ^N,κ^P-N(CH₂CH₂P ⁱ Pr₂)₂-Ligated Nickel Pincer Complexes.

Authors: Nadeesha P N Wellala; John D Luebking; Jeanette A Krause; Hairong Guan
Journal: ACS Omega Date: 2018-05-08

3. Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen.

Authors: Sophie W Anferov; Alexander S Filatov; John S Anderson
Journal: ACS Catal Date: 2022-08-01 Impact factor: 13.700

4. Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity.

Authors: Glenn R Morello; Hongyu Zhong; Paul J Chirik; Kathrin H Hopmann
Journal: Chem Sci Date: 2018-05-04 Impact factor: 9.825

Cobalt-catalyzed transfer hydrogenation of C=O and C=N bonds.

1. Alkene Metalates as Hydrogenation Catalysts.

2. Roles of Hydrogen Bonding in Proton Transfer to κ^P,κ^N,κ^P-N(CH₂CH₂P ⁱ Pr₂)₂-Ligated Nickel Pincer Complexes.

3. Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen.

4. Cobalt-catalysed alkene hydrogenation: a metallacycle can explain the hydroxyl activating effect and the diastereoselectivity.

5. Rational selection of co-catalysts for the deaminative hydrogenation of amides.

6. Transfer Hydrogenation of Ketones Catalyzed by Symmetric Imino-N-heterocyclic Carbene Co(III) Complexes.

7. Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism.