Literature DB >> 24045875

2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents.

Hikaru Yanai1, Yoichi Takahashi, Haruhiko Fukaya, Yasuo Dobashi, Takashi Matsumoto.   

Abstract

Stable and easy-to-handle zwitterions containing carbanion and pyridinium moieties were synthesized, and their structural studies by both X-ray crystallography and theoretical methods revealed the stereoelectronic effect in the zwitterionic 'C(-)-C-N(+)' system.

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Year:  2013        PMID: 24045875     DOI: 10.1039/c3cc46171h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis of δ-oxo-1,1-bis(triflyl)alkanes and their acidities.

Authors:  Hikaru Yanai; Masaya Fujita; Arata Takahashi; Min Zhang; Masaaki Mishima; Akira Kotani; Takashi Matsumoto; Takeo Taguchi
Journal:  Molecules       Date:  2013-12-13       Impact factor: 4.411

2.  Olefination with Sulfonyl Halides and Esters: Synthesis of Unsaturated Sulfonyl Fluorides.

Authors:  Michał Tryniszewski; Dariusz Basiak; Michał Barbasiewicz
Journal:  Org Lett       Date:  2022-06-02       Impact factor: 6.072

  2 in total

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