| Literature DB >> 24039019 |
Qiang Chen1, Ze Chang, Wei-Chao Song, Han Song, Hai-Bin Song, Tong-Liang Hu, Xian-He Bu.
Abstract
With H2 O or NH3 stimuli, the blue cobalt-based metal-organic framework (MOF) BP can reversibly transform to red RP. The removal/recovery of terephthalate ligands accompanied by the transformation leads to a gate effect, which allows the encapsulation and release of small solvent molecules under certain conditions. This is the first example of topology transformation from a self-penetrating to interpenetrating net in 3D MOFs.Entities:
Keywords: cobalt; gate effect; metal-organic frameworks; sensors; single-crystal transformation
Year: 2013 PMID: 24039019 DOI: 10.1002/anie.201306304
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336