| Literature DB >> 24038894 |
Elisa González-Fernández1, Jörg Rust, Manuel Alcarazo.
Abstract
No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was achieved by reaction of isocyanide gold complexes with phosphorus and arsenic ylides as well as electron-rich olefins. Their ability to form bimetallic species and to act as ligand-transfer reagents has also been established.Entities:
Keywords: acyclic carbenes; gold; ligand design; transmetalation; ylides
Year: 2013 PMID： 24038894 DOI： 10.1002/anie.201305311
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336