| Literature DB >> 24038888 |
Rueben Pfukwa1, Paul H J Kouwer, Alan E Rowan, Bert Klumperman.
Abstract
A biomimetic approach has been used for the templated self-assembly of a helical poly(para-aryltriazole) foldamer. The solvophobic folding process yields helices that further self-assemble into long nanotubes (see picture; scale bar: 100 nm). Constructs of controlled length and chirality can be generated by applying a poly(γ-benzyl-l-glutamate) scaffold at the appropriate assembly conditions, mimicking tobacco mosaic virus self-assembly.Entities:
Keywords: biomimetic synthesis; foldamers; information transfer; self-assembly; template
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Year: 2013 PMID: 24038888 DOI: 10.1002/anie.201303135
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336