| Literature DB >> 24038849 |
Guillaume Bélanger-Chabot1, Martin Rahm, Ralf Haiges, Karl O Christe.
Abstract
The marriage of fire and water: The strongly oxidizing trinitromethyl and strongly reducing BH3 groups were successfully combined for the first time in the novel [BH3 C(NO2 )3 ](-) ion. The stability at room temperature of the new (trinitromethyl)borate is in sharp contrast to the behavior of [BCl3 C(NO2 )3 ](-) , which already decomposes at -20 °C.Entities:
Keywords: borates; energetic materials; nitroformate; propellants; trinitromethyl
Year: 2013 PMID： 24038849 DOI： 10.1002/anie.201305602
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336