Literature DB >> 24038821

Chemical signals turn on guest binding through structural reconfiguration of triangular helicates.

Anne Sørensen1, Ana M Castilla, Tanya K Ronson, Michael Pittelkow, Jonathan R Nitschke.   

Abstract

Be my guest: The function of a system based on self-assembled Zn(II) complexes can be controlled by external chemical stimuli. The complexes are based on a C3 -symmetric ligand that forms a unique triangular triple helicate structure 1. Upon subcomponent substitution, 1 is able to transform into a triangular double helicate 2 which, unlike 1, can encapsulate guests.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  host-guest systems; metal-organic complexes; self-assembly; systems chemistry; zinc

Mesh:

Substances:

Year:  2013        PMID: 24038821     DOI: 10.1002/anie.201305245

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  4 in total

1.  Combining Synthesis and Self-Assembly in One Pot To Construct Complex 2D Metallo-Supramolecules Using Terpyridine and Pyrylium Salts.

Authors:  Heng Wang; Yiming Li; Hao Yu; Bo Song; Shuai Lu; Xin-Qi Hao; Yuan Zhang; Ming Wang; Saw-Wai Hla; Xiaopeng Li
Journal:  J Am Chem Soc       Date:  2019-08-07       Impact factor: 15.419

Review 2.  Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.

Authors:  Charlie T McTernan; Jack A Davies; Jonathan R Nitschke
Journal:  Chem Rev       Date:  2022-04-18       Impact factor: 72.087

3.  A pH-Switchable Triple Hydrogen-Bonding Motif.

Authors:  Heather M Coubrough; Barbora Balonova; Christopher M Pask; Barry A Blight; Andrew J Wilson
Journal:  ChemistryOpen       Date:  2020-01-08       Impact factor: 2.911

4.  Supramolecular Self-Sorting Networks using Hydrogen-Bonding Motifs.

Authors:  Heather M Coubrough; Stephanie C C van der Lubbe; Kristina Hetherington; Aisling Minard; Christopher Pask; Mark J Howard; Célia Fonseca Guerra; Andrew J Wilson
Journal:  Chemistry       Date:  2018-12-13       Impact factor: 5.236

  4 in total

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