Literature DB >> 24038642

Disentanglement of donation and back-donation effects on experimental observables: a case study of gold-ethyne complexes.

Giovanni Bistoni1, Leonardo Belpassi, Francesco Tarantelli.   

Abstract

A charge-displacement analysis of gold-ethyne complexes shows the existence of a quantitative relationship between measurable properties and the chemical bond constituents in the Dewar-Chatt-Duncanson model. Through suitable experiments, these constituents may be disentangled and crucial insight into the nature of coordination bonds may thus be gained.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkyne ligands; bond theory; density functional calculations; gold; multiple bonds

Year:  2013        PMID： 24038642     DOI： 10.1002/anie.201305505

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  Revisiting the Bonding Model for Gold(I) Species: The Importance of Pauli Repulsion Revealed in a Gold(I)-Cyclobutadiene Complex.

Authors:  Zeng Rong Wong; Tim K Schramm; Matthias Loipersberger; Martin Head-Gordon; F Dean Toste
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-30       Impact factor: 16.823

2.  Are homoleptic complexes of ethylene with group 12 metals isolable in solution? A DFT study.

Authors:  Mauro Fianchini; Nuno A G Bandeira
Journal:  J Mol Model       Date:  2018-06-14       Impact factor: 1.810

3.  How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes.

Authors:  Giovanni Bistoni; Sergio Rampino; Nicola Scafuri; Gianluca Ciancaleoni; Daniele Zuccaccia; Leonardo Belpassi; Francesco Tarantelli
Journal:  Chem Sci       Date:  2015-10-26       Impact factor: 9.825

4.  Cationic Gold(I) Diarylallenylidene Complexes: Bonding Features and Ligand Effects.

Authors:  Diego Sorbelli; Laura Nunes Dos Santos Comprido; Gerald Knizia; A Stephen K Hashmi; Leonardo Belpassi; Paola Belanzoni; Johannes E M N Klein
Journal:  Chemphyschem       Date:  2019-06-13       Impact factor: 3.102

5.  Orbital Decomposition of the Carbon Chemical Shielding Tensor in Gold(I) N-Heterocyclic Carbene Complexes.

Authors:  Maria A Izquierdo; Francesco Tarantelli; Ria Broer; Giovanni Bistoni; Leonardo Belpassi; Remco W A Havenith
Journal:  Eur J Inorg Chem       Date:  2020-03-12       Impact factor: 2.524

6.  Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C-H Insertion, and Dimerization Reactions.

Authors:  Cristina García-Morales; Xiao-Li Pei; Juan M Sarria Toro; Antonio M Echavarren
Journal:  Angew Chem Int Ed Engl       Date:  2019-02-11       Impact factor: 15.336
  6 in total

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