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Literature DB >> 24038302

Subcomponent self-assembly: a quick way to new metallogels.

Hana Bunzen¹, Elina Kalenius, Sami Hietala, Erkki Kolehmainen.

Abstract

1-2-3 gel! Subcomponent self-assembly is introduced as a new design route towards multistimuli-responsive metallogels. It offers a rapid and facile access to supramolecular gels and allows to design smart materials with diverse functional and structural properties by simply exchanging one (or more) of the components. Herein, the exchange of the metal ions is emphasized (see scheme).

Entities: Chemical

Keywords: gels; in situ gelation; multistimuli responsive; nanoparticles; self-assembly

Year: 2013 PMID： 24038302 DOI： 10.1002/chem.201302055

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

Keyword Cloud
Cited

9 in total

1. Subcomponent Exchange Transforms an Fe^II₄L₄ Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System.

Authors: Anna J McConnell; Catherine M Aitchison; Angela B Grommet; Jonathan R Nitschke
Journal: J Am Chem Soc Date: 2017-04-26 Impact factor: 15.419

7. Catalytic Gels for a Prebiotically Relevant Asymmetric Aldol Reaction in Water: From Organocatalyst Design to Hydrogel Discovery and Back Again.

Authors: Kirsten Hawkins; Anna K Patterson; Paul A Clarke; David K Smith
Journal: J Am Chem Soc Date: 2020-02-21 Impact factor: 15.419

Review 8. Life lessons.

Authors: Jonathan R Nitschke
Journal: Beilstein J Org Chem Date: 2015-11-27 Impact factor: 2.883

Review 9. Solid state NMR studies of gels derived from low molecular mass gelators.

Authors: E Kolehmainen
Journal: Soft Matter Date: 2016-07-13 Impact factor: 3.679

9 in total

Subcomponent self-assembly: a quick way to new metallogels.

1. Subcomponent Exchange Transforms an Fe^II₄L₄ Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System.

2. Dual stimuli-induced formation of a μ-hydroxido bridged [Zn₉L₅(μ-OH)₆]¹²⁺ half-pipe.

3. Excitation Energy Delocalization and Transfer to Guests within M^II₄L₆ Cage Frameworks.

4. Mutual stabilisation between M^II₄L₆ tetrahedra and M^IIX₄^2- metallate guests.

5. Slow Anion-Exchange Reaction of Cesium Lead Halide Perovskite Nanocrystals in Supramolecular Gel Networks.

6. Waterproof architectures through subcomponent self-assembly.

7. Catalytic Gels for a Prebiotically Relevant Asymmetric Aldol Reaction in Water: From Organocatalyst Design to Hydrogel Discovery and Back Again.

Review 8. Life lessons.

Review 9. Solid state NMR studies of gels derived from low molecular mass gelators.