Literature DB >> 24037274

Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]-H···H-[TMP].

Hasna Zaher1, Andrew E Ashley, Mark Irwin, Amber L Thompson, Matthias J Gutmann, Tobias Krämer, Dermot O'Hare.   

Abstract

The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H···H) bond within a hydrogenated FLP system.

Entities:  

Year:  2013        PMID: 24037274     DOI: 10.1039/c3cc45889j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Chemical reactivity of the frustrated Lewis pairs in borophosphines: a theoretical analysis of their Lewis acidity, Lewis basicity and Fukui function.

Authors:  Mariano Méndez; Andrés Cedillo
Journal:  J Mol Model       Date:  2018-08-17       Impact factor: 1.810

2.  Metal-free hydrogenation catalyzed by an air-stable borane: use of solvent as a frustrated Lewis base.

Authors:  Daniel J Scott; Matthew J Fuchter; Andrew E Ashley
Journal:  Angew Chem Int Ed Engl       Date:  2014-08-11       Impact factor: 15.336

3.  Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study.

Authors:  Nereida Hidalgo; Juan José Moreno; Inés García-Rubio; Jesús Campos
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-13       Impact factor: 16.823

  3 in total

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