| Literature DB >> 24037230 |
Beatriz Calvo1, Ramón Macías, Víctor Polo, María José Artigas, Fernando J Lahoz, Luis A Oro.
Abstract
A new mechanism of H2 activation is reported to occur on a carbene-ligated rhodathiaborane that features metal-thiaborane bifunctional synergistic effects. The key is the creation of vacant coordination sites by an isonido-nido structural transformation leading to the heterolytic H-H bond splitting.Entities:
Year: 2013 PMID： 24037230 DOI： 10.1039/c3cc45880f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222