Literature DB >> 24030658

Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal-organic framework.

Sridhar Regati1, Yabing He, Muralidhara Thimmaiah, Peng Li, Shengchang Xiang, Banglin Chen, John Cong-Gui Zhao.   

Abstract

The enantioselective ring-opening of meso-epoxides by aromatic amines was achieved by using a new chiral metal-organic framework . The corresponding α-hydroxyamines were obtained with good yields and ee values (up to 89% ee).

Entities:  

Year:  2013        PMID： 24030658     DOI： 10.1039/c3cc45988h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  A broadly applicable and practical oligomeric (salen) Co catalyst for enantioselective epoxide ring-opening reactions.

Authors:  David E White; Pamela M Tadross; Zhe Lu; Eric N Jacobsen
Journal:  Tetrahedron       Date:  2014-07-08       Impact factor: 2.457

2.  Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis.

Authors:  Xu Chen; Yongwu Peng; Xing Han; Yan Liu; Xiaochao Lin; Yong Cui
Journal:  Nat Commun       Date:  2017-12-19       Impact factor: 14.919

3.  Asymmetric ring-opening reaction of meso-epoxides with aromatic amines using homochiral metal-organic frameworks as recyclable heterogeneous catalysts.

Authors:  Koichi Tanaka; Maya Kinoshita; Jun Kayahara; Yutaro Uebayashi; Kazusada Nakaji; Maja Morawiak; Zofia Urbanczyk-Lipkowska
Journal:  RSC Adv       Date:  2018-08-06       Impact factor: 3.361

4.  The first chiral diene-based metal-organic frameworks for highly enantioselective carbon-carbon bond formation reactions.

Authors:  Takahiro Sawano; Pengfei Ji; Alexandra R McIsaac; Zekai Lin; Carter W Abney; Wenbin Lin
Journal:  Chem Sci       Date:  2015-09-14       Impact factor: 9.825
  4 in total

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