| Literature DB >> 24025201 |
Brett P Fors1, Justin E Poelma, Matthew S Menyo, Maxwell J Robb, Daniel M Spokoyny, John W Kramer, J Herbert Waite, Craig J Hawker.
Abstract
A modular and general method based on a photomediated ATRA reaction for the spatially controlled functionalization of surfaces with visible light is reported. The ability to control reactivity with light intensity combined with the orthogonality of ATRA chemistry allows well-defined chemically differentiated monolayers and complex nonlinear chemical concentration gradients to be easily prepared. Use of light to mediate these reactions permits spatial regulation and the generation of unique, multifunctional chemical gradients.Year: 2013 PMID： 24025201 DOI： 10.1021/ja408467b
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419