| Literature DB >> 24022579 |
De-Liang Long1, Jun Yan, Andreu Ruiz de la Oliva, Christoph Busche, Haralampos N Miras, R John Errington, Leroy Cronin.
Abstract
The new tungstatoiodate, α-[H5W18O59(IO3)](6-), containing I(V)O3(-) within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)](6-) by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I-O covalent bonds are broken.Entities:
Year: 2013 PMID： 24022579 DOI： 10.1039/c3cc45659e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222