Literature DB >> 24016239

A highly efficient luminescent Pt2Tl2 chain with a short Tl(I)-Tl(I) interaction.

Sirous Jamali1, Mona M Ashtiani, Zahra Jamshidi, Elena Lalinde, M Teresa Moreno, Hamidreza Samouei, Eduardo Escudero-Adán, Jordi Benet-Buchholz.   

Abstract

The preparation of an unsupported tetranuclear cluster with a linear Pt(0)-Tl(I)-Tl(I)-Pt(0) metal chain is described. The complex shows strong red emission in the solid state, having a quantum yield of 73%. Density functional theory (DFT) and time-dependent DFT calculations show that red emission originated from a platinum to thallium-thallium charge-transfer excited state.

Entities:  

Year:  2013        PMID： 24016239     DOI： 10.1021/ic401890t

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  One-Electron Oxidation of [M(P(t) Bu3 )2 ] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t) Bu3 )2 ](+) and Redox-Promoted C-H Bond Cyclometalation.

Authors:  Thibault Troadec; Sze-Yin Tan; Christopher J Wedge; Jonathan P Rourke; Patrick R Unwin; Adrian B Chaplin
Journal:  Angew Chem Int Ed Engl       Date:  2016-02-16       Impact factor: 15.336

2.  Metal-only Lewis pairs between group 10 metals and Tl(i) or Ag(i): insights into the electronic consequences of Z-type ligand binding.

Authors:  Brandon R Barnett; Curtis E Moore; Perumalreddy Chandrasekaran; Stephen Sproules; Arnold L Rheingold; Serena DeBeer; Joshua S Figueroa
Journal:  Chem Sci       Date:  2015-09-17       Impact factor: 9.825
  2 in total

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