Literature DB >> 24013296

Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine-diamine complexes.

Peili Zhang1, Mei Wang, Frederic Gloaguen, Lin Chen, François Quentel, Licheng Sun.   

Abstract

A cobalt complex with a tripyridine-diamine pentadentate ligand was found to be a highly active catalyst for electrochemical H2 production from neutral water, with an activity of 860 mol H2 (mol cat)(-1) h(-1) (cm(2) Hg)(-1) over 60 h CPE experiment at -1.25 V in a pH 7 phosphate buffer solution, without considerable deactivation.

Entities:  

Year:  2013        PMID： 24013296     DOI： 10.1039/c3cc43491e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Crystal structure and electrochemical properties of [Ni(bztmpen)(CH3CN)](BF4)2 {bztmpen is N-benzyl-N,N',N'-tris-[(6-methyl-pyridin-2-yl)meth-yl]ethane-1,2-di-amine}.

Authors:  Lin Chen; Gan Ren; Yakun Guo; Ge Sang
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-05-09

2.  Bioinspired design of redox-active ligands for multielectron catalysis: effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water.

Authors:  Jonah W Jurss; Rony S Khnayzer; Julien A Panetier; Karim A El Roz; Eva M Nichols; Martin Head-Gordon; Jeffrey R Long; Felix N Castellano; Christopher J Chang
Journal:  Chem Sci       Date:  2015-06-09       Impact factor: 9.825

3.  Remarkable stability of a molecular ruthenium complex in PEM water electrolysis.

Authors:  Marco Bellini; Jonas Bösken; Michael Wörle; Debora Thöny; Juan José Gamboa-Carballo; Frank Krumeich; Francesco Bàrtoli; Hamish A Miller; Lorenzo Poggini; Werner Oberhauser; Alessandro Lavacchi; Hansjörg Grützmacher; Francesco Vizza
Journal:  Chem Sci       Date:  2022-03-03       Impact factor: 9.825

4.  Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation.

Authors:  Debashis Basu; Shivnath Mazumder; Jens Niklas; Habib Baydoun; Dakshika Wanniarachchi; Xuetao Shi; Richard J Staples; Oleg Poluektov; H Bernhard Schlegel; Cláudio N Verani
Journal:  Chem Sci       Date:  2016-02-02       Impact factor: 9.825
  4 in total

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