Literature DB >> 24007944

Using SPMDs to monitor the seawater concentrations of PAHs and PCBs in marine protected areas (Western Mediterranean).

Alessandro Marrucci1, Barbara Marras1, Susanna S Campisi2, Marco Schintu3.   

Abstract

Aqueous concentrations of individual polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were determined in coastal sites of two marine protected areas (MPAs), that is, Asinara and the La Maddalena Archipelago, in Sardinia (Western Mediterranean Sea). The use of semi-permeable membrane devices (SPMDs) enabled the detection of dissolved PAHs and PCBs, even in very low concentrations of (pgL(-1)), in seawater. The results reveal significant differences between the two sampling areas relative to the concentration of the individual PAHs, which provide information concerning the pollution sources affecting relatively pristine environments. The PCBs were generally observed at levels below the detection limits of the utilised method.
Copyright © 2013 Elsevier Ltd. All rights reserved.

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Keywords:  AS; Ace; Aceph; Ant; Asinara Island National Marine Reserve; BaA; BaP; BbF; BeP; BgP; BkF; CID; CRK; Chemical Reaction Kinetic; Chr; Collision Induced Dissociation; DBA; Fl; Flu; HPAH; InP; Kow; LDPE; LM; LPAH; La Maddalena Archipelago National Park; MPA; Naph; OCP; PAHs; PCBs; POP; PRCs; PS; Passive sampling; Per; Phen; Pyr; SIS; SPMD; SPMDs; Single Ion Storage; WFD; Water Framework Directive; Western Mediterranean; acenaphthene; acenaphthylene; anthracene; benz[a]anthracene; benzo[a]pyrene; benzo[b]fluoranthene; benzo[e]pyrene; benzo[ghi]perylene; benzo[k]fluoranthene; chrysene; dibenzo[a,h]anthracene; fluoranthene; fluorene; high-weight polycyclic aromatic hydrocarbons (Flu, Pyr, BaA, Chr, BbF, BkF, BaP, DBA, BgP, Inp); indeno[1,2,3-cd]pyrene; low-density polyethylene; low-weight polycyclic aromatic hydrocarbons (Naph, Aceph, Ace, Fl, Phen, Ant); marine protected area; naphthalene; octanol–water partition coefficient; organochlorurate pesticides; passive sampling; performance reference compounds; persistent organic pollutant; perylene; phenanthrene; polychlorinated biphenyls; polycyclic aromatic hydrocarbons; pyrene; semi-permeable membrane devices

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Year:  2013        PMID: 24007944     DOI: 10.1016/j.marpolbul.2013.08.004

Source DB:  PubMed          Journal:  Mar Pollut Bull        ISSN: 0025-326X            Impact factor:   5.553


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