Literature DB >> 23999534

σ-Coordination of metal-boryl bonds to gold(I).

Holger Braunschweig1, Krzysztof Radacki, Rong Shang.   

Abstract

The first examples of σ-coordinated metal-haloboryl complexes have been synthesised. The haloboryl moiety may be functionalized by nucleophilic substitution reactions, by which more electron-withdrawing substituents may be installed at the boron center.

Entities:  

Year:  2013        PMID： 23999534     DOI： 10.1039/c3cc45455j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments.

Authors:  Holger Braunschweig; Krzysztof Radacki; Rong Shang
Journal:  Chem Sci       Date:  2015-03-10       Impact factor: 9.825

2.  Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.

Authors:  Lingbing Kong; Rakesh Ganguly; Yongxin Li; Rei Kinjo
Journal:  Chem Sci       Date:  2015-02-23       Impact factor: 9.825

3.  Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls.

Authors:  Bennett J Eleazer; Mark D Smith; Alexey A Popov; Dmitry V Peryshkov
Journal:  Chem Sci       Date:  2018-02-05       Impact factor: 9.825

4.  A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals.

Authors:  Xiaofeng Mao; Jie Zhang; Zhenpin Lu; Zuowei Xie
Journal:  Chem Sci       Date:  2022-02-11       Impact factor: 9.825
  4 in total

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