Literature DB >> 23987582

Ruthenium-catalyzed hydroformylation/reduction of olefins to alcohols: extending the scope to internal alkenes.

Lipeng Wu1, Ivana Fleischer, Ralf Jackstell, Irina Profir, Robert Franke, Matthias Beller.   

Abstract

In the presence of 2-phosphino-substituted imidazole ligands and Ru3(CO)12 or Ru(methylallyl)2(COD) direct hydroformylation and hydrogenation of alkenes to alcohols takes place. In addition to terminal alkenes, also more challenging internal olefins are converted preferentially to industrially important linear alcohols in high yield (up to 88%) and regioselectivity (n:iso up to 99:1).

Entities:  

Year:  2013        PMID： 23987582     DOI： 10.1021/ja4060977

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

Review 1.  Remote functionalization through alkene isomerization.

Authors:  Alexandre Vasseur; Jeffrey Bruffaerts; Ilan Marek
Journal:  Nat Chem       Date:  2016-03       Impact factor: 24.427

2.  Reaction of FcC[triple bond, length as m-dash]CC(O)R (Fc = ferrocenyl) with Ru3(CO)12 leading to unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted triruthenium clusters.

Authors:  Lei Xu; Liping Jiang; Shasha Li; Guofang Zhang; Weiqiang Zhang; Ziwei Gao
Journal:  RSC Adv       Date:  2018-07-16       Impact factor: 4.036

3.  A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-opening.

Authors:  Sukhdev Singh; Jeffrey Bruffaerts; Alexandre Vasseur; Ilan Marek
Journal:  Nat Commun       Date:  2017-02-07       Impact factor: 14.919

4.  Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.

Authors:  Alexandre Vasseur; Lionel Perrin; Odile Eisenstein; Ilan Marek
Journal:  Chem Sci       Date:  2015-03-03       Impact factor: 9.825

5.  Ligand-Controlled Palladium-Catalyzed Carbonylation of Alkynols: Highly Selective Synthesis of α-Methylene-β-Lactones.

Authors:  Yao Ge; Fei Ye; Jiawang Liu; Ji Yang; Anke Spannenberg; Haijun Jiao; Ralf Jackstell; Matthias Beller
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-17       Impact factor: 15.336

6.  Iridium-Catalyzed Domino Hydroformylation/Hydrogenation of Olefins to Alcohols: Synergy of Two Ligands.

Authors:  Weiheng Huang; Xinxin Tian; Haijun Jiao; Ralf Jackstell; Matthias Beller
Journal:  Chemistry       Date:  2022-01-10       Impact factor: 5.020
  6 in total

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