Literature DB >> 23987140

Cyclohexanones by Rh-mediated intramolecular C-H insertion.

Douglass F Taber1, Craig M Paquette, Peiming Gu, Weiwei Tian.   

Abstract

Some long chain α-aryl α-diazo ketones under Rh catalysis cyclize efficiently to the corresponding cyclohexanones. This is in marked contrast to the cyclizations of α-diazo β-ketoesters, which consistently deliver cyclopentanone products.

Entities:  

Year:  2013        PMID： 23987140     DOI： 10.1021/jo4014996

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

1.  Photodegradable Antimicrobial Agents: Synthesis and Mechanism of Degradation.

Authors:  Vebjørn Eikemo; Bjarte Holmelid; Leiv K Sydnes; Magne O Sydnes
Journal:  J Org Chem       Date:  2022-06-02       Impact factor: 4.198

2.  Do GluN2B subunit containing NMDA receptors tolerate a fluorine atom in the phenylalkyl side chain?

Authors:  Yoshihiro Shuto; Simone Thum; Louisa Temme; Dirk Schepmann; Masato Kitamura; Bernhard Wünsch
Journal:  Medchemcomm       Date:  2017-03-17       Impact factor: 3.597

3.  C-H Insertion via Ruthenium Catalyzed gem-Hydrogenation of 1,3-Enynes.

Authors:  Sebastian Peil; Alejandro Gutiérrez González; Markus Leutzsch; Alois Fürstner
Journal:  J Am Chem Soc       Date:  2022-02-16       Impact factor: 15.419

4.  Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C-H insertion of donor/donor carbenes.

Authors:  Leslie A Nickerson; Benjamin D Bergstrom; Mingchun Gao; Yuan-Shin Shiue; Croix J Laconsay; Matthew R Culberson; Walker A Knauss; James C Fettinger; Dean J Tantillo; Jared T Shaw
Journal:  Chem Sci       Date:  2019-11-13       Impact factor: 9.825
  4 in total

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