| Literature DB >> 23984832 |
Yuji Mikata1, Anna Ugai, Risa Ohnishi, Hideo Konno.
Abstract
Dinuclear zinc complex [Zn2(TQHPN)(AcO)](2+) exhibits characteristic fluorescence response (λex = 317 nm and λem = 455 nm) toward pyrophosphate (PPi) with maximum fluorescence upon 1:1 Zn2(TQHPN)-PPi complex formation. The crystallographic investigation utilizing P(1)P(2)-Ph2PPi revealed that the fluorescent response mechanism is due to intramolecular excimer formation of two quinoline rings.Entities:
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Year: 2013 PMID: 23984832 DOI: 10.1021/ic401605m
Source DB: PubMed Journal: Inorg Chem ISSN: 0020-1669 Impact factor: 5.165