Literature DB >> 23981278

Insertion of zerovalent nickel into the N-N bond of N-heterocyclic-carbene-activated N2O.

Alexander G Tskhovrebov1, Euro Solari, Rosario Scopelliti, Kay Severin.   

Abstract

Metal-mediated cleavage of the N-N bond is a rarely observed phenomenon in the chemistry of nitrous oxide (N2O). We demonstrate that, upon activation of N2O with N-heterocyclic carbenes, zerovalent nickel is able to insert into the N-N bond to give nitrosyl complexes.

Entities:  

Year:  2013        PMID： 23981278     DOI： 10.1021/ic401524w

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Towards Anion Recognition and Precipitation with Water-Soluble 1,2,4-Selenodiazolium Salts: Combined Structural and Theoretical Study.

Authors:  Alexey A Artemjev; Anton P Novikov; Gleb M Burkin; Alexander A Sapronov; Alexey S Kubasov; Valentine G Nenajdenko; Victor N Khrustalev; Alexander V Borisov; Anatoly A Kirichuk; Andreii S Kritchenkov; Rosa M Gomila; Antonio Frontera; Alexander G Tskhovrebov
Journal:  Int J Mol Sci       Date:  2022-06-07       Impact factor: 6.208

2.  De novo design and synthesis of dipyridopurinone derivatives as visible-light photocatalysts in productive guanylation reactions.

Authors:  Yameng Wan; Hao Wu; Nana Ma; Jie Zhao; Zhiguo Zhang; Wenjing Gao; Guisheng Zhang
Journal:  Chem Sci       Date:  2021-11-13       Impact factor: 9.825

3.  Exploring Supramolecular Assembly Space of Cationic 1,2,4-Selenodiazoles: Effect of the Substituent at the Carbon Atom and Anions.

Authors:  Mariya V Grudova; Alexey S Kubasov; Victor N Khrustalev; Alexander S Novikov; Andreii S Kritchenkov; Valentine G Nenajdenko; Alexander V Borisov; Alexander G Tskhovrebov
Journal:  Molecules       Date:  2022-02-02       Impact factor: 4.411
  3 in total

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