Literature DB >> 23976815

Decomposition of a Mixed-Valence [2Fe-2S] Cluster to Linear Tetra-Ferric and Ferrous Clusters.

Caroline T Saouma1, Werner Kaminsky, James M Mayer.   

Abstract

Despite the ease of preparing di-ferric [2Fe-2S] clusters, preparing stable mixed-valence analogues remains a challenge, as these clusters have limited thermal stability. Herein we identify two decomposition products of the mixed-valence thiosalicylate-ligated [2Fe-2S] cluster, [Fe2S2(SArCOO)2]3- ((SArCOO)2- = thiosalicylate).

Entities:  

Keywords:  clusters; iron; sulfur

Year:  2013        PMID： 23976815      PMCID： PMC3747655          DOI： 10.1016/j.poly.2012.07.057

Source DB:  PubMed          Journal:  Polyhedron        ISSN： 0277-5387            Impact factor:   3.052


  11 in total

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9.  Protonation and concerted proton-electron transfer reactivity of a bis-benzimidazolate ligated [2Fe-2S] model for Rieske clusters.

Authors:  Caroline T Saouma; Werner Kaminsky; James M Mayer
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3.  Electron transfer and proton-coupled electron transfer reactivity and self-exchange of synthetic [2Fe-2S] complexes: models for Rieske and mitoNEET clusters.

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