Literature DB >> 23970307

Copper-catalyzed free-radical C-H arylation of pyrroles.

Aurélien Honraedt1, Marie-Audrey Raux, Erwan Le Grognec, Denis Jacquemin, François-Xavier Felpin.   

Abstract

A room temperature copper-catalyzed radical arylation of pyrroles with anilines, through in situ generated aryl diazonium salts, has been developed under neutral conditions. Experimental and theoretical studies explain the crucial role of CaCO3 and the high regioselectivity observed.

Entities:  

Year:  2013        PMID： 23970307     DOI： 10.1039/c3cc45240a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Diels-Alder cycloadditions of N-arylpyrroles via aryne intermediates using diaryliodonium salts.

Authors:  Huangguan Chen; Jianwei Han; Limin Wang
Journal:  Beilstein J Org Chem       Date:  2018-02-06       Impact factor: 2.883

2.  Mild and selective base-free C-H arylation of heteroarenes: experiment and computation.

Authors:  Hannes P L Gemoets; Indrek Kalvet; Alexander V Nyuchev; Nico Erdmann; Volker Hessel; Franziska Schoenebeck; Timothy Noël
Journal:  Chem Sci       Date:  2016-09-05       Impact factor: 9.825
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.