| Literature DB >> 23963373 |
Hefeng Zhang1, Nazeeha Alkayal, Yves Gnanou, Nikos Hadjichristidis.
Abstract
A novel one-pot methodology combining anionic polymerization and polyhomologation, through a "bridge" molecule (BF3OEt2), was developed for the synthesis of polyethylene (PE)-based block copolymers. The anionically synthesized macroanion reacts with the "bridge" molecule to afford a 3-arm star (trimacromolecular borane) which serves as an initiator for the polyhomologation.Entities:
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Year: 2013 PMID： 23963373 DOI： 10.1039/c3cc44928a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222