Literature DB >> 23963189

Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols.

Dexi Yang1, Glenn C Micalizio.   

Abstract

Azatitanacyclopropanes (titanaziridines) are shown to be stereochemically labile under reaction conditions for reductive cross-coupling. This fundamental property has been employed to realize highly selective asymmetric coupling reactions with allylic alcohols that proceed by dynamic kinetic resolution.

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Year:  2013        PMID： 23963189      PMCID： PMC4012230          DOI： 10.1039/c3cc45607b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  33 in total

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Authors:  B M Trost; J L Gunzner
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2.  Total synthesis of macbecin I.

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3.  Total synthesis of callystatin a by titanium-mediated reductive alkyne-alkyne cross-coupling.

Authors:  Holly A Reichard; Jude C Rieger; Glenn C Micalizio
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4.  Regioselective Reductive Cross-Coupling Reactions of Unsymmetrical Alkynes.

Authors:  Holly A Reichard; Martin McLaughlin; Ming Z Chen; Glenn C Micalizio
Journal:  European J Org Chem       Date:  2010-01

5.  Total synthesis of lehualide B by allylic alcohol-alkyne reductive cross-coupling.

Authors:  Valer Jeso; Glenn C Micalizio
Journal:  J Am Chem Soc       Date:  2010-08-25       Impact factor: 15.419

6.  Total synthesis of (+/-)-asteriscanolide.

Authors:  M E Krafft; Y Y Cheung; K A Abboud
Journal:  J Org Chem       Date:  2001-11-02       Impact factor: 4.354

7.  Convergent and stereodivergent synthesis of complex 1-aza-7-oxabicyclo[2.2.1]heptanes.

Authors:  Dexi Yang; Glenn C Micalizio
Journal:  J Am Chem Soc       Date:  2011-05-23       Impact factor: 15.419

8.  Alkene-alkyne coupling as a linchpin: an efficient and convergent synthesis of amphidinolide P.

Authors:  Barry M Trost; Julien P N Papillon
Journal:  J Am Chem Soc       Date:  2004-10-27       Impact factor: 15.419

9.  Synthesis of prostaglandin and phytoprostane B1 via regioselective intermolecular Pauson-Khand reactions.

Authors:  Ana Vázquez-Romero; Lydia Cárdenas; Emma Blasi; Xavier Verdaguer; Antoni Riera
Journal:  Org Lett       Date:  2009-07-16       Impact factor: 6.005

10.  Synthesis of alkaloid (-)-205B via stereoselective reductive cross-coupling and intramolecular [3+2] cycloaddition.

Authors:  Dexi Yang; Glenn C Micalizio
Journal:  J Am Chem Soc       Date:  2012-09-07       Impact factor: 15.419
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  1 in total

1.  Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.

Authors:  Vikram Bhat; Eric R Welin; Xuelei Guo; Brian M Stoltz
Journal:  Chem Rev       Date:  2017-02-06       Impact factor: 60.622
  1 in total

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