| Literature DB >> 23959638 |
Kundan C Tayade1, Anil S Kuwar, Umesh A Fegade, Hemant Sharma, Narinder Singh, Umesh D Patil, Sanjay B Attarde.
Abstract
A pyridine based imine-linked chemosensor has been synthesized and evaluated its binding affinity with library of transition metal ions. It has prominent selectivity towards Pb2+ among other metal ions in DMF/H2O (9:1, v/v) solvent system. The 1:1 stoichiometric was confirmed by job's plot and has a binding constant (Ka) = 5.142 × 103 M-1 on fluorescence. A B3LYP/6-31G and B3LYP/LanL2DZ basis sets were employed for optimization of 3 and 3.Pb2+.Entities:
Year: 2013 PMID: 23959638 DOI: 10.1007/s10895-013-1287-6
Source DB: PubMed Journal: J Fluoresc ISSN: 1053-0509 Impact factor: 2.217