Literature DB >> 23948951

Developing catalytic applications of cooperative bimetallics: competitive hydroamination/trimerization reactions of isocyanates catalysed by sodium magnesiates.

Alberto Hernán-Gómez1, Tyne D Bradley, Alan R Kennedy, Zoe Livingstone, Stuart D Robertson, Eva Hevia.   

Abstract

Mixed-metal reagents [NaMg(CH2SiMe3)3] (1) and [(THF)NaMg(NPh2)3(THF)] [3-(THF)(2)] can act as precatalysts to selectively promote the hydroamination/trimerization of isocyanates (RNCO) depending on the steric bulk of the R substituent.

Entities:  

Year:  2013        PMID： 23948951     DOI： 10.1039/c3cc45167d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  THF-solvated Heavy Alkali Metal Benzyl Compounds (Na, Rb, Cs): Defined Deprotonation Reagents for Alkali Metal Mediation Chemistry.

Authors:  Lukas Brieger; Christian Unkelbach; Carsten Strohmann
Journal:  Chemistry       Date:  2021-10-25       Impact factor: 5.020

2.  1,3,5-Triaryl-1,3,5-Triazinane-2,4,6-Trithiones: Synthesis, Electronic Structure and Linear Optical Properties.

Authors:  Ismaël Rabouel; Nicolas Richy; Anissa Amar; Abdou Boucekkine; Thierry Roisnel; Olivier Mongin; Mark G Humphrey; Frédéric Paul
Journal:  Molecules       Date:  2020-11-23       Impact factor: 4.411

3.  Lewis Acid Assisted Brønsted Acid Catalysed Decarbonylation of Isocyanates: A Combined DFT and Experimental Study.

Authors:  Ayan Dasgupta; Yara van Ingen; Michael G Guerzoni; Kaveh Farshadfar; Jeremy M Rawson; Emma Richards; Alireza Ariafard; Rebecca L Melen
Journal:  Chemistry       Date:  2022-06-21       Impact factor: 5.020

Review 4.  Main group bimetallic partnerships for cooperative catalysis.

Authors:  Jose M Gil-Negrete; Eva Hevia
Journal:  Chem Sci       Date:  2020-10-16       Impact factor: 9.825
  4 in total

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