Literature DB >> 23947634

A Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes.

Yang-Xiong Li1, Qing-Qing Xuan, Li Liu, Dong Wang, Yong-Jun Chen, Chao-Jun Li.   

Abstract

A direct dehydrative coupling of terminal alkynes with allylic alcohols catalyzed by Pd(PPh3)4 with an N,P-ligand assisted by Ti(OiPr)4 has been developed. The coupling reaction tolerates various functional groups, providing a valuable synthetic tool to access 1,4-enynes.

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Year:  2013        PMID: 23947634     DOI: 10.1021/ja406025p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  4 in total

1.  Iminophosphanes: Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles.

Authors:  Mark K Rong; Koen van Duin; Tom van Dijk; Jeroen J M de Pater; Berth-Jan Deelman; Martin Nieger; A W Ehlers; J Chris Slootweg; Koop Lammertsma
Journal:  Organometallics       Date:  2017-02-16       Impact factor: 3.876

2.  Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols.

Authors:  Xue-Gong Jia; Peng Guo; Jicheng Duan; Xing-Zhong Shu
Journal:  Chem Sci       Date:  2017-11-06       Impact factor: 9.825

3.  Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism.

Authors:  Da-Chang Bai; Fei-Le Yu; Wan-Ying Wang; Di Chen; Hao Li; Qing-Rong Liu; Chang-Hua Ding; Bo Chen; Xue-Long Hou
Journal:  Nat Commun       Date:  2016-06-10       Impact factor: 14.919

4.  Rhodium-catalyzed asymmetric hydroamination and hydroindolation of keto-vinylidenecyclopropanes.

Authors:  Song Yang; Quan-Zhe Li; Chen Xu; Qin Xu; Min Shi
Journal:  Chem Sci       Date:  2018-05-11       Impact factor: 9.825

  4 in total

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