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Literature DB >> 23946186

Thermodynamics of molecules strongly coupled to the vacuum field.

Antoine Canaguier-Durand¹, Eloïse Devaux, Jino George, Yantao Pang, James A Hutchison, Tal Schwartz, Cyriaque Genet, Nadine Wilhelms, Jean-Marie Lehn, Thomas W Ebbesen.

Abstract

The thermodynamics of strong coupling between molecules and the vacuum field is analyzed and the Gibbs free energy, the enthalpy, and entropy of the coupling process are determined for the first time. The thermodynamic parameters are a function of the Rabi splitting and the microscopic solvation. The results provide a new framework for understanding light-molecule strong coupling.

Keywords: strong coupling; thermodynamics; vacuum field

Year: 2013 PMID： 23946186 DOI： 10.1002/anie.201301861

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

9 in total

1. Conductivity in organic semiconductors hybridized with the vacuum field.

Authors: E Orgiu; J George; J A Hutchison; E Devaux; J F Dayen; B Doudin; F Stellacci; C Genet; J Schachenmayer; C Genes; G Pupillo; P Samorì; T W Ebbesen
Journal: Nat Mater Date: 2015-09-14 Impact factor: 43.841

2. Charge-transfer dynamics and nonlocal dielectric permittivity tuned with metamaterial structures as solvent analogues.

Authors: Kwang Jin Lee; Yiming Xiao; Jae Heun Woo; Eunsun Kim; David Kreher; André-Jean Attias; Fabrice Mathevet; Jean-Charles Ribierre; Jeong Weon Wu; Pascal André
Journal: Nat Mater Date: 2017-06-05 Impact factor: 43.841

Thermodynamics of molecules strongly coupled to the vacuum field.

1. Conductivity in organic semiconductors hybridized with the vacuum field.

2. Charge-transfer dynamics and nonlocal dielectric permittivity tuned with metamaterial structures as solvent analogues.

3. Enhanced Raman Scattering from Vibro-Polariton Hybrid States.

4. Quantum-electrodynamical time-dependent density functional theory within Gaussian atomic basis.

5. Coherent coupling of molecular resonators with a microcavity mode.

6. Modified relaxation dynamics and coherent energy exchange in coupled vibration-cavity polaritons.

7. Optical-field driven charge-transfer modulations near composite nanostructures.

8. Selective manipulation of electronically excited states through strong light-matter interactions.

Review 9. Strong light-matter interactions: a new direction within chemistry.