Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 A one-pot synthesis of a triblock copolymer from propylene oxide/carbon dioxide and lactide: intermediacy of polyol initiators.

Literature DB >> 23946153

A one-pot synthesis of a triblock copolymer from propylene oxide/carbon dioxide and lactide: intermediacy of polyol initiators.

Abstract

Just add water: The copolymerization of propylene oxide and CO2 catalyzed by a cobalt complex is tolerant to the addition of water as chain-transfer reagent to afford polyols (HO-(PPC)-OH) with narrow molecular weight distributions (see picture; PPC=poly(propylene carbonate); PLA=polylactide). The addition of an organocatalyst to these polyols in the presence of lactides produces well-defined triblock copolymers (PLA-b-PPC-b-PLA).

Entities: Chemical

Keywords: block copolymers; carbon dioxide; coordination copolymerization; lactide; ring-opening polymerization

Year: 2013 PMID： 23946153 DOI： 10.1002/anie.201304778

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

8 in total

Review 1. Sustainable polymers from renewable resources.

Authors: Yunqing Zhu; Charles Romain; Charlotte K Williams
Journal: Nature Date: 2016-12-14 Impact factor: 49.962

2. Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications.

Authors: Arron C Deacy; Georgina L Gregory; Gregory S Sulley; Thomas T D Chen; Charlotte K Williams
Journal: J Am Chem Soc Date: 2021-06-30 Impact factor: 15.419

3. Chemoselective polymerization control: from mixed-monomer feedstock to copolymers.

Authors: Dr Charles Romain; Charlotte K Williams
Journal: Angew Chem Int Ed Engl Date: 2014-01-22 Impact factor: 15.336

4. Di-Zinc-Aryl Complexes: CO₂ Insertions and Applications in Polymerisation Catalysis.

Authors: Charles Romain; Jennifer A Garden; Gemma Trott; Antoine Buchard; Andrew J P White; Charlotte K Williams
Journal: Chemistry Date: 2017-05-05 Impact factor: 5.236

5. Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone.

Authors: Yang Li; Jiali Hong; Renjian Wei; Yingying Zhang; Zaizai Tong; Xinghong Zhang; Binyang Du; Junting Xu; Zhiqiang Fan
Journal: Chem Sci Date: 2014-12-08 Impact factor: 9.825

A one-pot synthesis of a triblock copolymer from propylene oxide/carbon dioxide and lactide: intermediacy of polyol initiators.

Review 1. Sustainable polymers from renewable resources.

2. Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications.

3. Chemoselective polymerization control: from mixed-monomer feedstock to copolymers.

4. Di-Zinc-Aryl Complexes: CO₂ Insertions and Applications in Polymerisation Catalysis.

5. Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone.

6. Multiblock copolymers of PPC with oligomeric PBS: with low brittle-toughness transition temperature.

7. Direct Copolymerization of CO2 and Diols.

8. A New Dinuclear Cobalt Complex for Copolymerization of CO₂ and Propylene Oxide: High Activity and Selectivity.