Literature DB >> 23944607

Difluorodioxophosphate-based hollow hexanuclear lanthanide(III) clusters decorated with tetrathiafulvalene ligands.

Tamyris T da Cunha1, Fabrice Pointillart, Boris Le Guennic, Cynthia L M Pereira, Stéphane Golhen, Olivier Cador, Lahcène Ouahab.   

Abstract

The galvanostatic reaction of the [4,5-bis(2-pyridyl-N-oxidemethylthio)]-4',5'-methyldithiotetrathiafulvalene ligand with lanthanide ions in the presence of hexafluorophosphate (PF6(-)) anions afforded the highest-nuclearity lanthanide clusters decorated by tetrathiafulvalene-based ligands thanks to the original partial hydrolysis of the PF6(-) anions in difluorodioxophosphate (PO2F2(-)) bridging ligands.

Entities:  

Year:  2013        PMID: 23944607     DOI: 10.1021/ic4012839

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165



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