Literature DB >> 23942548

Acylsilanes: valuable organosilicon reagents in organic synthesis.

Hui-Jun Zhang1, Daniel L Priebbenow, Carsten Bolm.   

Abstract

Acylsilanes are a fascinating class of compounds that display a number of distinctive chemical and physical properties. The unique reactivity pattern of the acylsilane functional group [R-C(O)Si] makes them an increasingly attractive moiety in modern organic synthesis, and as such, they have been utilised in a diverse range of transformations. This review provides an overview of the recent advances in the synthesis and application of acylsilanes in organic chemistry, with a particular focus on the progress made in the last two decades.

Entities:  

Year:  2013        PMID: 23942548     DOI: 10.1039/c3cs60185d

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN: 0306-0012            Impact factor:   54.564


  8 in total

1.  Acyl Radical Chemistry via Visible-Light Photoredox Catalysis.

Authors:  Arghya Banerjee; Zhen Lei; Ming-Yu Ngai
Journal:  Synthesis (Stuttg)       Date:  2018-12-12       Impact factor: 3.157

2.  Borane catalysed ring opening and closing cascades of furans leading to silicon functionalized synthetic intermediates.

Authors:  Chinmoy K Hazra; Narasimhulu Gandhamsetty; Sehoon Park; Sukbok Chang
Journal:  Nat Commun       Date:  2016-11-28       Impact factor: 14.919

3.  Direct synthesis and applications of solid silylzinc reagents.

Authors:  Revathi Chandrasekaran; Feba Thomas Pulikkottil; Krishna Suresh Elama; Ramesh Rasappan
Journal:  Chem Sci       Date:  2021-11-30       Impact factor: 9.825

4.  Intramolecular photochemical [2 + 1]-cycloadditions of nucleophilic siloxy carbenes.

Authors:  Amanda Bunyamin; Carol Hua; Anastasios Polyzos; Daniel L Priebbenow
Journal:  Chem Sci       Date:  2022-02-25       Impact factor: 9.825

5.  Photo-Brook rearrangement of acyl silanes as a strategy for photoaffinity probe design.

Authors:  Annika C S Page; Spencer O Scholz; Katherine N Keenan; Jessica N Spradlin; Bridget P Belcher; Scott M Brittain; John A Tallarico; Jeffrey M McKenna; Markus Schirle; Daniel K Nomura; F Dean Toste
Journal:  Chem Sci       Date:  2022-03-11       Impact factor: 9.825

6.  Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon.

Authors:  Ya Wu; Hua Chen; Wenyu Yang; Yu Fan; Lu Gao; Zhishan Su; Changwei Hu; Zhenlei Song
Journal:  RSC Adv       Date:  2019-08-21       Impact factor: 4.036

7.  Cascade cyclization of alkene-tethered acylsilanes and allylic sulfones enabled by unproductive energy transfer photocatalysis.

Authors:  Yunxiao Zhang; Yizhi Zhang; Chen Ye; Xiaotian Qi; Li-Zhu Wu; Xiao Shen
Journal:  Nat Commun       Date:  2022-10-16       Impact factor: 17.694

8.  The Exploration of Aroyltrimethylgermane as Potent Synthetic Origins and Their Preparation.

Authors:  Yang Yuan; Youcan Zhang; Bo Chen; Xiao-Feng Wu
Journal:  iScience       Date:  2019-12-14
  8 in total

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