Literature DB >> 23942463

A decatungstate-type polyoxoniobate with centered manganese: [H2Mn(IV)Nb10O32]8- as a soluble tetramethylammonium salt.

Jung-Ho Son1, William H Casey.   

Abstract

A highly symmetric Mn(IV)-centered polyoxoniobate [H2Mn(IV)Nb10O32](8-) was synthesized via hydrothermal methods as a soluble tetramethylammonium salt. The structure is similar to decatungstate structure [W10O32](4-), except for the central heteroatom. The cluster is stable between 4 < pH < 10, as was characterized with ESI-MS and UV-Vis spectroscopy.

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Year:  2013        PMID： 23942463     DOI： 10.1039/c3dt51798e

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

Review 1.  Beyond Charge Balance: Counter-Cations in Polyoxometalate Chemistry.

Authors:  Archismita Misra; Karoly Kozma; Carsten Streb; May Nyman
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-31       Impact factor: 15.336

2.  Niobium-substituted octahedral molecular sieve (OMS-2) materials in selective oxidation of methanol to dimethoxymethane.

Authors:  Niluka D Wasalathanthri; Curtis Guild; Quddus A Nizami; Shanka L Dissanayake; Junkai He; Peter Kerns; Jared Fee; Laura Achola; Dinithi Rathnayake; Chandima Weerakkody; Steven L Suib; Partha Nandi
Journal:  RSC Adv       Date:  2019-10-14       Impact factor: 4.036
  2 in total

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